Several years back now, Brett Anderson of Suede claimed that in 90% of cases the seventh track of an album (excluding compilations or best-ofs etc) was the best. A friend told him the theory and he'd gone through his collection and discoverd it was true.
Anyway, I did the same and found it does work. About 80% of albums I'd say. It's still freaky.
The seventh track on YATQ is 'How Could Anybody Know...' which I think will be a lot of people's favourite.
I know this sounds crazy but get a heap of CDs and try it for yourself.
By the way - two things to consider. It DEFINATELY doesn't apply on Southpaw Grammar and also, Brett was on heroin.